Ferric acetylacetonate
Contact usQuality manufacturer supply Ferric acetylacetonate 14024-18-1 in stock with high standard
- Molecular Formula: C15H21FeO6
- Molecular Weight: 353.175
- Appearance/Colour: dark red powder
- Vapor Pressure: 0.174mmHg at 25°C
- Melting Point: 180-182 °C (dec.)(lit.)
- Boiling Point: 110 °C 2 mm
- Flash Point: 43.1ºC
- PSA： 102.42000
- Density: 5.24 g/mL at 25 °C(lit.)
- LogP: 1.66100
Ferric acetylacetonate(Cas 14024-18-1) Usage
|
Preparation |
Ferric acetylacetonate is prepared by shaking ferric hydroxide with an alcoholic solution of the reagent. It is an excellent quencher of triplet states. |
|
General Description |
This product has been enhanced for catalytic efficiency. |
|
Flammability and Explosibility |
Notclassified |
|
Purification Methods |
When recrystallised twice from *benzene/pet ether, it has m 181.3-182.3o corr [Finn et al. J Chem Soc 1256 1938]. However, when recrystallised from EtOH or Et2O it has m 179o [Hantzsch & Desch Justus Liebigs Ann Chem 323 13 1902]. Recrystallisation from absolute EtOH gives material with m 159.5o [Emmert & Jacob Chem Ber 67 286 1934]. Dry it for 1hour at 120o. [Beilstein 1 IV 606, 2 IV 1908.] |
InChI:InChI=1/3C5H8O2.Fe/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;
14024-18-1 Relevant articles
RATE OF LIGAND EXCHANGE OF TRIS(ACETYLACETONATO)IRON(III) WITH TRIFLUOROACETYLACETONE AND TRIS(TRIFLUOROACETYLACETONATO)IRON(III) WITH ACETYLACETONE
Sekine, Tatsuya,Inaba, Kazuho
, p. 1669 - 1672 (1983)
The rate of ligand exchange of tris(acet...
ELECTRON PARAMAGNETIC RESONANCE OF FERRIC ACETYL ACETONATE.
Hedewy,Hoffmann
, p. 129 - 133 (1986)
X and Q band EPR spectra for Fe(acac)//3...
The direct electrochemical synthesis of transition metal acetylacetonates
Long,Lagowski
, p. 813 - 815 (2007)
Acetylacetonates were prepared electroch...
A Novel [Fe(acac)3] Interspersed g-C3N4 Heterostructure for Environmentally Benign Visible-Light-Driven Oxidation of Alcohols
Devi, Meghali,Ganguly, Sreejeeb,Bhuyan, Bishal,Dhar, Siddhartha Sankar,Vadivel, Sethumathavan
, p. 4819 - 4825 (2018)
The present work describes facile synthe...
Achirality in the low temperature structure and lattice modes of tris(acetylacetonate)iron(III)
Ellis, Thomas K.,Kearley, Gordon J.,Piltz, Ross O.,Jayasooriya, Upali A.,Stride, John A.
, p. 8278 - 8283 (2016)
Tris(acetylacteonate) iron(iii) is a rel...
Investigation of nanocrystalline phases in Li-La-Fe-O system formed by the decomposition of acetylacetonato complexes
Vu?ini?-Vasi?,Antic,Kremenovi?,Nikolic,Blanusa,Raki?,Spasojevic,Kapor
, p. 322 - 326 (2007)
Applying a new synthesis route based on ...
Isomerism, molecular structure, and vibrational assignment of tris(triflouroacetylacetonato)iron(III): An experimental and theoretical study
Gandomi, Farzad,Takjoo, Reza,Tayyari, Sayyed Faramarz,Vakili, Mohammad
, (2022)
The isomerism, optimized molecular struc...
Effect of technique of applying layers of metal acetylacetonates on acid-base and chromatographic properties of sorbents
Slizhov, Yu. G.,Matveeva,Minakova
, p. 1376 - 1382 (2013)
A series of chromatographic sorbents, wh...
Preparation and characterisation of crystalline tris(acetylacetonato)Fe(III) films grown on p-Si substrate for dielectric applications
Dakhel,Ali-Mohamed
, p. 162 - 167 (2007)
Thin tris(acetylacetonato)iron(III) film...
Immobilisation of iron tris(β-diketonates) on a two-dimensional flat amine functionalised silicon wafer: A catalytic study of the formation of urethane, from ethanol and a diisocyanate derivative
Conradie,Conradie,Erasmus
, p. 52 - 59 (2014)
A series of immobilised iron tris(β-dike...
Novel Synthesis of Tris(acetylacetonato)iron(III)
Chaudhuri, Mihir K.,Ghosh, Soumitra K.
, p. 839 - 840 (1983)
The reaction of iron(III) hydroxide with...
Kinetics and Mechanism of Ligand Exchange of Tris(acetylacetonato)-iron(III) in Acetylacetone
Kido, Hiroaki,Saito, Kazuo
, p. 424 - 428 (1980)
Tris(acetylacetonato)iron(III) undergoes...
The pentacyanonitrosylferrate(2-) ion. IV. Reactions with the carbanions of pentane-2,4-dione and 3-methylpentane-2,4-dione
Butler, Anthony R.,Calsy, Adrianne M.,Glidewell, Christopher
, p. 439 - 446 (1988)
The products from the reaction of pentan...
Optimized molecular geometry, vibrational analysis, and Fe-O bond strength of Tris(α-cyanoacetylacetonate)iron(III):An experimental and theoretical study
Darugar, Vahidreza,Gandomi, Farzad,Takjoo, Reza,Tayyari, Sayyed Faramarz,Vakili, Mohammad
, (2021/09/16)
Tris(α-cyanoacetylacetonate)iron(III), F...
14024-18-1 Process route
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Fe(2+) *3NO3 (1-) *9H2 O
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-
123-54-6,81235-32-7
acetylacetone
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-
14024-18-1
iron(III)-acetylacetonate
| Conditions | Yield |
|---|---|
|
In
ethanol; dichloromethane;
for 0.5h;
|
73%
|
-
-
iron(III) chloride hexahydrate
-
-
123-54-6,81235-32-7
acetylacetone
-
-
14024-18-1
iron(III)-acetylacetonate
| Conditions | Yield |
|---|---|
|
iron(III) chloride hexahydrate;
With
potassium hydroxide;
In
water;
pH=8;
acetylacetone;
In
methanol; water;
at 70 - 75 ℃;
for 0.333333h;
|
|
|
With
sodium acetate;
In
ethanol;
for 0.5h;
|
14024-18-1 Upstream products
-
123-54-6
acetylacetone
-
13463-40-6
iron pentacarbonyl
-
121714-78-1
iron(III) chloride hexahydrate
-
19393-11-4
potassium acetylacetonate
14024-18-1 Downstream products
-
220203-23-6
trans-4-(4-methylcyclohexyl)-4-oxobutanoic acid
-
1345-25-1
iron(II) oxide
-
7439-89-6
iron
-
14534-87-3
dibenzoato iron(II)
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