Medicarpin
Contact usChina cas 32383-76-9 factory wholesale Medicarpin at affordable price
- Molecular Formula: C16H14O4
- Molecular Weight: 270.285
- Vapor Pressure: 1.31E-07mmHg at 25°C
- Melting Point: 127.5-128.5°
- Refractive Index: 1.629
- Boiling Point: 418.8 °C at 760 mmHg
- PKA: 9.50±0.20(Predicted)
- Flash Point: 207.1 °C
- PSA： 47.92000
- Density: 1.319 g/cm3
- LogP: 3.01050
Medicarpin(Cas 32383-76-9) Usage
InChI:InChI=1/C16H14O4/c1-18-10-3-5-11-13-8-19-14-6-9(17)2-4-12(14)16(13)20-15(11)7-10/h2-7,13,16-17H,8H2,1H3/t13-,16-/m0/s1
32383-76-9 Relevant articles
A general asymmetric route to enantio-enriched isoflavanes via an organocatalytic annulation of o-quinone methides and aldehydes
Zhang, Jian,Zhang, Shuangzhan,Yang, Huixin,Zhou, Ding,Yu, Xueting,Wang, Wei,Xie, Hexin
supporting information, p. 2407 - 2411 (2018/05/24)
Reported herein is a general approach to...
Unified total syntheses of (-)-medicarpin, (-)-sophoracarpan a, and (±)-kushecarpin a with some structural revisions
Feng, Zhen-Gao,Bai, Wen-Ju,Pettus, Thomas R. R.
supporting information, p. 1864 - 1867 (2015/02/19)
The total syntheses of medicarpin, sopho...
Synthesis, optical resolution, absolute configuration, and osteogenic activity of cis-pterocarpans
Goel, Atul,Kumar, Amit,Hemberger, Yasmin,Raghuvanshi, Ashutosh,Jeet, Ram,Tiwari, Govind,Knauer, Michael,Kureel, Jyoti,Singh, Anuj K.,Gautam, Abnish,Trivedi, Ritu,Singh, Divya,Bringmann, Gerhard
, p. 9583 - 9592 (2013/01/16)
A convenient synthesis of natural and sy...
Catalytic specificity of pea O-methyltransferases suggests gene duplication for (+)-pisatin biosynthesis
Akashi, Tomoyoshi,VanEtten, Hans D.,Sawada, Yuji,Wasmann, Catherine C.,Uchiyama, Hiroshi,Ayabe, Shin-ichi
, p. 2525 - 2530 (2007/10/03)
S-adenosyl-l-methionine: 2-hydroxyisofla...
32383-76-9 Process route
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C30 H28 O4
-
-
32383-76-9
medicarpin
-
-
33983-39-0
medicarpin
| Conditions | Yield |
|---|---|
|
C30H28O4;
With
lead(II,IV) oxide; acetic acid;
In
benzene;
at 85 ℃;
for 3h;
With
10 wt% Pd(OH)2 on carbon; hydrogen;
In
tetrahydrofuran; ethanol;
at 20 ℃;
With
potassium carbonate;
In
ethyl acetate;
at 20 ℃;
Overall yield = 49 %; Overall yield = 13 mg; enantioselective reaction;
|
88 % ee
|
-
-
C18 H18 O6
-
-
32383-76-9
medicarpin
| Conditions | Yield |
|---|---|
|
With
potassium carbonate;
In
ethyl acetate;
at 20 ℃;
for 5h;
|
112 mg
|
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770722-02-6
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-
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-
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32383-76-9 Downstream products
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52766-70-8
medicarpin 3-O-glucoside
-
1690-62-6
3-hydroxy-9-methoxy-6H-benzofuro[3,2-c]chromen-6-one
-
33983-39-0
medicarpin
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